Thermal Expansion

 

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TM 15 Thermal Expansion

B. S. 1902:1952 described the test method for thermal expansion. This has been replaced by BS 1902 : Section 5.3 : 1990 Thermal Expansion of Refractory materials (Horizontal method to 1100oC). The method for determination of linear thermal expansion of ceramic tiles is described in BS EN 10545-8 : 1996.

This technique can be used to plot the change in size (similarly to the Firing under Load test) of raw clays, to estimate the degree of calcination of flint, estimate the proportion of free silica in certain clays. However, it is more commonly used to:-

Measure the thermal expansion of refractories  to ensure optimum performance of kiln furniture, furnace linings, etc.. during use.

Measure the thermal expansion of clay bodies and glazes to ensure good glaze fit. Ideally a glaze should be in compression at all temperatures during the product’s use. If a glaze is in tension it tends to craze and with too much compression is likely to peal.

Special ceramics used as engine components must have similar properties to the materials that it is bonded too, to avoid cracking.

The test involves preparing a sample 75 mm long with a cross section of 10 mm for most ceramic products. In the white-ware industry sample bars around 50 mm long with a cross section of 3mm tend to be used for purely comparisons of clay bodies.

The test specimen is dried and then allowed to cool in a desiccator, the length measured to the nearest 0.1mm and then placed into the expansion apparatus. Malkin in conjunction with British Ceramic Research Association designed the original apparatus, which utilised a tube furnace to heat the specimen and a dial gauge to indicate the distance moved by the push rod and hence the thermal expansion. Many companies automated this original design by fitting a kiln controller to control the furnace and a linear transducer linked to a plotter to measure the expansion.

A few companies linked the transducer to data loggers, which could log the voltage output from the transducer and temperature via a thermocouple place near the test specimen (Instead of relying on the kilns thermocouple in the original design) simultaneously.

In recent years computers have been used to both control the furnace and monitor the specimens temperature and the linear movement, automatically applying correction factors and producing both a graph and a table of results.

These developments have reduced the labour involved, i.e. the original equipment needed a technician to manually control the temperature and take regular temperature and dial gauge readings.  Modern equipment utilising SCADA Monitoring and Control Systems such as in the FGH design or  S. L Electrotech’s computer controlled system take a few minutes to set up and can be left unattended.

The automated equipment is very accurate with repeatability on S. L Electrotech’s apparatus better than 0.09% Thermal Expansion. Results on a wide range of digital equipment seam to be produced to a large number of decimal places, although we advise our customers to treat only the first two decimal places as been accurate.

 

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Last modified: October 31, 2000